The Reds made light work of Accrington Stanley in the last round, but may face a tougher test away from home against Championship opposition.
However, they still have the quality required to dispose of the struggling second-division side.
And if needed, they can call on their bench to add some extra quality if Liverpool find themselves in trouble.
Read on to see how both line-up.
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Plymouth line-up
Your Greens to face Liverpool! 💚 pic.twitter.com/D4Sw1i5WFO
— Plymouth Argyle FC (@Argyle) February 9, 2025
The hosts have adopted a more defensive shape to try and keep their opponents at bay.
Conor Hazard is in goal, behind a three of Maksym Talovierov, Nikola Katic and Julio Pleguezuelo.
At wing back, Plymouth have Matthew Sorinola and Tymoreusz Puchacz.
Adam Randell and Darko Gyabi hold the midfield, with Mustapha Bundu and Ryan Hardie ahead.
Callum Wright leads the line.
Liverpool line-up
Team news is IN 🙌 #EmiratesFACup
— Liverpool FC (@LFC) February 9, 2025
As expected, Slot has mixed things up.
Caoimhin Kelleher is in goal, with Trey Nyoni, Jarell Quansah, Joe Gomez and Konstantinos Tsimikas in defence.
Harvey Elliott is joined in midfield by Wataro Endo and James McConnell.
Federico Chiesa and Luis Diaz occupy the wide areas.
And Diogo Jota is the main man up front.
